Study of heavy metal pollution of the Upper-Tisza floodplain using XRF techniques


Study of heavy metal pollution of the Upper-Tisza floodplain using XRF techniques

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Title: Study of heavy metal pollution of the Upper-Tisza floodplain using XRF techniques
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Article_Title: Study of heavy metal pollution of the Upper-Tisza floodplain using XRF techniques
Authors: László Csedreki 1, István Csatári 3, Szilárd Szabó 2
Affiliation: 1Institute of Nuclear Research of the Hungarian Academy of Science, H-4026 Debrecen, Hungary
2University of Debrecen, Department of Landscape Protection and Environmental Geography, H-4032 Debrecen, Hungary
3University of Debrecen, Department of Applied Ecology, H-4032 Debrecen, Hungary
Abstract: The increased level of heavy-metals in the sediments of floodplains is strongly related to the Romanian metalwork. Different heavy metals (eg. Cu, Zn, Pb) often accumulate in the silt of the ore spoil bank and they can become a serious source of environmental pollution. In this study the heavy metal content of the floodplain of the Tisza-Kraszna crossing was determined with the help of energy-dispersive X-ray fluorescence spectrometry (ED-XRF), and particle induced X-ray emission (PIXE) method. Cu and Zn concentration values were compared with data obtained from Flame Atomic Absorption Spectrometry (F-AAS). The depth profile of the sampling territory was determined for Cu, Zn, and Pb concentrations. We carried out toxicological experiments with Synapis alba germination and root elongation to decide how the exceedance of the limit of geological agent affected the vegetation.
Keywords: heavy metal content, PIXE, ED-XRF, F-AAS
References: Bacsó J., Pázsit Á. And Somogyi A. (1998): Energy Dispersive X-Ray Fluorescence Analysis in: Vértes A., Nagy S., Süvegh K., Nuclear Methods in Mineralogy and Geology (Techniques and Applications), Plenum Press, New York p. 165-215 (A cikk tartalmazza a módszeer ismertetését angolul.)
Csatári I., Keresztúri P., Tóth A., Lakatos Gy. (2009): Accumulation of heavy metals in different parts of plants species. Trace Elements in the food chain, Volume 3, 292-296.
Djingova R., Kuleff I., (2000): Trace elements-Their distribution and effects in the environment B. Markert and K. Friese, editors 2000 Elsevier Science B. V. Chapter 5 Instrumental techniques for trace analysis p. 158-159
Kertész Zs., Szoboszlai Z., Angyal A., Dobos E., Borbély-Kiss I.: Identification and characterization of fine and coarse particulte matter sources in a middle-European urban environment, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 268 (2010) 1924-1928
Kertész Zs., Szikszai Z., Uzonyi I., Simon A., Kiss, Á. Z (2005).: Development of a bio-PIXE setup at the Debrecen scanning proton microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 231 106-111.
Kertész Zs., Szikszai Z., Szoboszlai Z., Simon A., Huszánk R., Uzonyi I (2009).: Study of individual atmospheric aerosol particles at the Debrecen ion microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 267 (2009) 2236-2240
Kis-Varga M., Bacsó J. (1976) : Investigations for determining the optimum measurement geometry of Si/Li/detector X-ray spectrometer. SCI Journal of Radioanalytical Chemistry 31 (1976)407-X./ 0.6611976
Rabnecz Gy., Papp B., Vegvary Gy. (2007): Comparison of heavy metal deposition by large scale biomonitoring in Europe and tropical Africa. Cereal Research Communications 35, 961-965.
Rajta I.,,Borbely-Kiss I., Morik Gy.,,Bartha L.,, Koltay E.,, Kiss A. Z.: The new Atomki scanning proton microprobe.Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 109 (1996)148-153
Somogyi A., Braun M., Posta J. (1997): Analytical Note, Comparison between X-ray fluorescens and inductively coupled plasma atomic emission spectrometry in the analysis of sediment sample . Spectrochimica Acta Part B 52, 2011-2017.
Szabó Sz., Molnár L. Sz., Gosztonyi Gy., Posta J., Prokisch J. (2008): A nehézfém-szennyezettség vizsgálata egy felső-tiszai holtmeder környezetében In: Demeter G.,(Szerk.), Geografia generalis et specialis., Debrecen, p.255-260
Szabó Gy (2009), PIXEKLM Program, User Guide, ATOMKI, Debrecen, 2009.
Szabó Gy., Borbély-Kiss I. (1993): PIXYKLM computer package for PIXE analyses.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 75 123-X./ 1.157
Uzonyi I., Rajta I., Bartha L., Kiss Á. Z., Nagy, A. (2001): Realization of the simultaneous micro-PIXE analysis of heavy and light elements at a nuclear microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 181 193-198.
www.geo-log.hu/uploads/docs/6_2009_kvvm.pdf, 6/2009. (IV.4.) KöM-EüM-FVM-KHVM a földtani közeg és a felszín alatti víz szennyezéssel szembeni védelméhez szükséges határértékekről és a szennyezések mérésérő
Read_full_article: pdf/21-2011/21-1-2011/SU21-1-2011Csedreki.pdf
Correspondence: László Csedreki, Institute of Nuclear Research of the Hungarian Academy of Science, Laboratory of Ion Beam Applications, Bem tér 18/c, H-4032, Debrecen, Hungary, E-mail: csedreki@atomki.hu

Read full article
Article Title: Study of heavy metal pollution of the Upper-Tisza floodplain using XRF techniques
Authors: László Csedreki 1, István Csatári 3, Szilárd Szabó 2
Affiliation: 1Institute of Nuclear Research of the Hungarian Academy of Science, H-4026 Debrecen, Hungary
2University of Debrecen, Department of Landscape Protection and Environmental Geography, H-4032 Debrecen, Hungary
3University of Debrecen, Department of Applied Ecology, H-4032 Debrecen, Hungary
Abstract: The increased level of heavy-metals in the sediments of floodplains is strongly related to the Romanian metalwork. Different heavy metals (eg. Cu, Zn, Pb) often accumulate in the silt of the ore spoil bank and they can become a serious source of environmental pollution. In this study the heavy metal content of the floodplain of the Tisza-Kraszna crossing was determined with the help of energy-dispersive X-ray fluorescence spectrometry (ED-XRF), and particle induced X-ray emission (PIXE) method. Cu and Zn concentration values were compared with data obtained from Flame Atomic Absorption Spectrometry (F-AAS). The depth profile of the sampling territory was determined for Cu, Zn, and Pb concentrations. We carried out toxicological experiments with Synapis alba germination and root elongation to decide how the exceedance of the limit of geological agent affected the vegetation.
Keywords: heavy metal content, PIXE, ED-XRF, F-AAS
References: Bacsó J., Pázsit Á. And Somogyi A. (1998): Energy Dispersive X-Ray Fluorescence Analysis in: Vértes A., Nagy S., Süvegh K., Nuclear Methods in Mineralogy and Geology (Techniques and Applications), Plenum Press, New York p. 165-215 (A cikk tartalmazza a módszeer ismertetését angolul.)
Csatári I., Keresztúri P., Tóth A., Lakatos Gy. (2009): Accumulation of heavy metals in different parts of plants species. Trace Elements in the food chain, Volume 3, 292-296.
Djingova R., Kuleff I., (2000): Trace elements-Their distribution and effects in the environment B. Markert and K. Friese, editors 2000 Elsevier Science B. V. Chapter 5 Instrumental techniques for trace analysis p. 158-159
Kertész Zs., Szoboszlai Z., Angyal A., Dobos E., Borbély-Kiss I.: Identification and characterization of fine and coarse particulte matter sources in a middle-European urban environment, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 268 (2010) 1924-1928
Kertész Zs., Szikszai Z., Uzonyi I., Simon A., Kiss, Á. Z (2005).: Development of a bio-PIXE setup at the Debrecen scanning proton microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 231 106-111.
Kertész Zs., Szikszai Z., Szoboszlai Z., Simon A., Huszánk R., Uzonyi I (2009).: Study of individual atmospheric aerosol particles at the Debrecen ion microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 267 (2009) 2236-2240
Kis-Varga M., Bacsó J. (1976) : Investigations for determining the optimum measurement geometry of Si/Li/detector X-ray spectrometer. SCI Journal of Radioanalytical Chemistry 31 (1976)407-X./ 0.6611976
Rabnecz Gy., Papp B., Vegvary Gy. (2007): Comparison of heavy metal deposition by large scale biomonitoring in Europe and tropical Africa. Cereal Research Communications 35, 961-965.
Rajta I.,,Borbely-Kiss I., Morik Gy.,,Bartha L.,, Koltay E.,, Kiss A. Z.: The new Atomki scanning proton microprobe.Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 109 (1996)148-153
Somogyi A., Braun M., Posta J. (1997): Analytical Note, Comparison between X-ray fluorescens and inductively coupled plasma atomic emission spectrometry in the analysis of sediment sample . Spectrochimica Acta Part B 52, 2011-2017.
Szabó Sz., Molnár L. Sz., Gosztonyi Gy., Posta J., Prokisch J. (2008): A nehézfém-szennyezettség vizsgálata egy felső-tiszai holtmeder környezetében In: Demeter G.,(Szerk.), Geografia generalis et specialis., Debrecen, p.255-260
Szabó Gy (2009), PIXEKLM Program, User Guide, ATOMKI, Debrecen, 2009.
Szabó Gy., Borbély-Kiss I. (1993): PIXYKLM computer package for PIXE analyses.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 75 123-X./ 1.157
Uzonyi I., Rajta I., Bartha L., Kiss Á. Z., Nagy, A. (2001): Realization of the simultaneous micro-PIXE analysis of heavy and light elements at a nuclear microprobe. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 181 193-198.
www.geo-log.hu/uploads/docs/6_2009_kvvm.pdf, 6/2009. (IV.4.) KöM-EüM-FVM-KHVM a földtani közeg és a felszín alatti víz szennyezéssel szembeni védelméhez szükséges határértékekről és a szennyezések mérésérő
*Correspondence: László Csedreki, Institute of Nuclear Research of the Hungarian Academy of Science, Laboratory of Ion Beam Applications, Bem tér 18/c, H-4032, Debrecen, Hungary, E-mail: csedreki@atomki.hu